Vikki Ziegler, known as the Divorce Diva, is trying to change the way couples go through the process of divorcing. She thinks going to court and letting a judge decide "who gets what" is so yesterday. Ziegler advises her clients to have the process done outside of court. She offers to mediate and divide the assets without having to go through the long, drawn-out legal process when couples turn to her. Assisting are brothers Mark and Michael Millea, professional appraisers who assess the values of the couple's belongings, to help Ziegler split the assets as evenly as possible. Who needs a judge when the Divorce Diva can take care of the separation instead on Untying the Knot?